A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation

Agus R. Poerwoprajitno; Lucy Gloag; John Watt; Soshan Cheong; Xin Tan; Han Lei; Hassan A. Tahini; Aaron Henson; Bijil Subhash; Nicholas M. Bedford; Benjamin K. Miller; Peter B. O’Mara; Tania M. Benedetti; Dale L. Huber; Wenhua Zhang; Sean C. Smith; J. Justin Gooding; Wolfgang Schuhmann; Richard D. Tilley

doi:10.1038/s41929-022-00756-9

A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation

Agus R. Poerwoprajitno
, Lucy Gloag
, John Watt
, Soshan Cheong
, Xin Tan
, Han Lei
, Hassan A. Tahini
, Aaron Henson
, Bijil Subhash
, Nicholas M. Bedford
, Benjamin K. Miller
, Peter B. O’Mara
, Tania M. Benedetti
, Dale L. Huber
, Wenhua Zhang
, Sean C. Smith
, J. Justin Gooding
, Wolfgang Schuhmann
, Richard D. Tilley

Los Alamos National Laboratory

Research output: Contribution to journal › Article › peer-review

336 Scopus citations

Abstract

Single Pt atom catalysts are key targets because a high exposure of Pt substantially enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active catalysts for the methanol oxidation reaction. To combine the exceptional activity of single Pt atom catalysts with an active Ru support we must overcome the synthetic challenge of forming single Pt atoms on noble metal nanoparticles. Here we demonstrate a process that grows and spreads Pt islands on Ru branched nanoparticles to create single-Pt-atom-on-Ru catalysts. By following the spreading process by in situ TEM, we found that the formation of a stable single atom structure is thermodynamically driven by the formation of strong Pt–Ru bonds and the lowering of the surface energy of the Pt islands. The stability of the single-Pt-atom-on-Ru structure and its resilience to CO poisoning result in a high current density and mass activity for the methanol oxidation reaction over time. [Figure not available: see fulltext.]

Original language	English
Pages (from-to)	231-237
Number of pages	7
Journal	Nature Catalysis
Volume	5
Issue number	3
DOIs	https://doi.org/10.1038/s41929-022-00756-9
State	Published - Mar 2022

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Poerwoprajitno, A. R., Gloag, L., Watt, J., Cheong, S., Tan, X., Lei, H., Tahini, H. A., Henson, A., Subhash, B., Bedford, N. M., Miller, B. K., O’Mara, P. B., Benedetti, T. M., Huber, D. L., Zhang, W., Smith, S. C., Gooding, J. J., Schuhmann, W., & Tilley, R. D. (2022). A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation. Nature Catalysis, 5(3), 231-237. https://doi.org/10.1038/s41929-022-00756-9

@article{08deddcf41104c24a7b341b8e53f3ac3,

title = "A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation",

abstract = "Single Pt atom catalysts are key targets because a high exposure of Pt substantially enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active catalysts for the methanol oxidation reaction. To combine the exceptional activity of single Pt atom catalysts with an active Ru support we must overcome the synthetic challenge of forming single Pt atoms on noble metal nanoparticles. Here we demonstrate a process that grows and spreads Pt islands on Ru branched nanoparticles to create single-Pt-atom-on-Ru catalysts. By following the spreading process by in situ TEM, we found that the formation of a stable single atom structure is thermodynamically driven by the formation of strong Pt{\textendash}Ru bonds and the lowering of the surface energy of the Pt islands. The stability of the single-Pt-atom-on-Ru structure and its resilience to CO poisoning result in a high current density and mass activity for the methanol oxidation reaction over time. [Figure not available: see fulltext.]",

author = "Poerwoprajitno, \{Agus R.\} and Lucy Gloag and John Watt and Soshan Cheong and Xin Tan and Han Lei and Tahini, \{Hassan A.\} and Aaron Henson and Bijil Subhash and Bedford, \{Nicholas M.\} and Miller, \{Benjamin K.\} and O{\textquoteright}Mara, \{Peter B.\} and Benedetti, \{Tania M.\} and Huber, \{Dale L.\} and Wenhua Zhang and Smith, \{Sean C.\} and Gooding, \{J. Justin\} and Wolfgang Schuhmann and Tilley, \{Richard D.\}",

year = "2022",

month = mar,

doi = "10.1038/s41929-022-00756-9",

language = "English",

volume = "5",

pages = "231--237",

journal = "Nature Catalysis",

number = "3",

}

Poerwoprajitno, AR, Gloag, L, Watt, J, Cheong, S, Tan, X, Lei, H, Tahini, HA, Henson, A, Subhash, B, Bedford, NM, Miller, BK, O’Mara, PB, Benedetti, TM, Huber, DL, Zhang, W, Smith, SC, Gooding, JJ, Schuhmann, W & Tilley, RD 2022, 'A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation', Nature Catalysis, vol. 5, no. 3, pp. 231-237. https://doi.org/10.1038/s41929-022-00756-9

TY - JOUR

T1 - A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation

AU - Poerwoprajitno, Agus R.

AU - Gloag, Lucy

AU - Watt, John

AU - Cheong, Soshan

AU - Tan, Xin

AU - Lei, Han

AU - Tahini, Hassan A.

AU - Henson, Aaron

AU - Subhash, Bijil

AU - Bedford, Nicholas M.

AU - Miller, Benjamin K.

AU - O’Mara, Peter B.

AU - Benedetti, Tania M.

AU - Huber, Dale L.

AU - Zhang, Wenhua

AU - Smith, Sean C.

AU - Gooding, J. Justin

AU - Schuhmann, Wolfgang

AU - Tilley, Richard D.

PY - 2022/3

Y1 - 2022/3

N2 - Single Pt atom catalysts are key targets because a high exposure of Pt substantially enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active catalysts for the methanol oxidation reaction. To combine the exceptional activity of single Pt atom catalysts with an active Ru support we must overcome the synthetic challenge of forming single Pt atoms on noble metal nanoparticles. Here we demonstrate a process that grows and spreads Pt islands on Ru branched nanoparticles to create single-Pt-atom-on-Ru catalysts. By following the spreading process by in situ TEM, we found that the formation of a stable single atom structure is thermodynamically driven by the formation of strong Pt–Ru bonds and the lowering of the surface energy of the Pt islands. The stability of the single-Pt-atom-on-Ru structure and its resilience to CO poisoning result in a high current density and mass activity for the methanol oxidation reaction over time. [Figure not available: see fulltext.]

AB - Single Pt atom catalysts are key targets because a high exposure of Pt substantially enhances electrocatalytic activity. In addition, PtRu alloy nanoparticles are the most active catalysts for the methanol oxidation reaction. To combine the exceptional activity of single Pt atom catalysts with an active Ru support we must overcome the synthetic challenge of forming single Pt atoms on noble metal nanoparticles. Here we demonstrate a process that grows and spreads Pt islands on Ru branched nanoparticles to create single-Pt-atom-on-Ru catalysts. By following the spreading process by in situ TEM, we found that the formation of a stable single atom structure is thermodynamically driven by the formation of strong Pt–Ru bonds and the lowering of the surface energy of the Pt islands. The stability of the single-Pt-atom-on-Ru structure and its resilience to CO poisoning result in a high current density and mass activity for the methanol oxidation reaction over time. [Figure not available: see fulltext.]

UR - https://www.scopus.com/pages/publications/85127281793

U2 - 10.1038/s41929-022-00756-9

DO - 10.1038/s41929-022-00756-9

M3 - Article

VL - 5

SP - 231

EP - 237

JO - Nature Catalysis

JF - Nature Catalysis

IS - 3

ER -

A single-Pt-atom-on-Ru-nanoparticle electrocatalyst for CO-resilient methanol oxidation

Abstract

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