An electron spin resonance study of fremy's salt in a dilute polycrystalline environment

M. T. Jones; Stuart Alan Trugman; V. Rapini; R. Hameed

doi:10.1021/j100522a015

An electron spin resonance study of fremy's salt in a dilute polycrystalline environment

M. T. Jones
, Stuart Alan Trugman
, V. Rapini
, R. Hameed

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The ESR spectrum of Fremy's salt, (KSO₃)₂NO, in a dilute polycrystalline matrix has been recorded. The matrix used is the usual diamagnetic, yellow-orange form of Fremy's salt. The spectrum has been analyzed and the anisotropic magnetic resonance parameters which describe it have been measured. The value of the parameters so obtained are as follows: g₁ = 2.00832 (±0.00002); g₂ = 2.00589 (±0.00005); g₃ = 2.00259 (±0.00005); A₁ = 5.5 (±0.1); A₂ = 5.5 (±0.1); A₃ = 28.9 (±0.2). Not surprisingly, it is found that these parameters depend upon the matrix in which the Fremy's salt is found.

Original language	English
Pages (from-to)	664-665
Number of pages	2
Journal	Journal of Physical Chemistry
Volume	81
Issue number	7
DOIs	https://doi.org/10.1021/j100522a015
State	Published - Jan 1 1977
Externally published	Yes

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@article{a17f51571069407b910e14f1f63d9594,

title = "An electron spin resonance study of fremy's salt in a dilute polycrystalline environment",

abstract = "The ESR spectrum of Fremy's salt, (KSO3)2NO, in a dilute polycrystalline matrix has been recorded. The matrix used is the usual diamagnetic, yellow-orange form of Fremy's salt. The spectrum has been analyzed and the anisotropic magnetic resonance parameters which describe it have been measured. The value of the parameters so obtained are as follows: g1 = 2.00832 (±0.00002); g2 = 2.00589 (±0.00005); g3 = 2.00259 (±0.00005); A1 = 5.5 (±0.1); A2 = 5.5 (±0.1); A3 = 28.9 (±0.2). Not surprisingly, it is found that these parameters depend upon the matrix in which the Fremy's salt is found.",

author = "Jones, \{M. T.\} and Trugman, \{Stuart Alan\} and V. Rapini and R. Hameed",

year = "1977",

month = jan,

day = "1",

doi = "10.1021/j100522a015",

language = "English",

volume = "81",

pages = "664--665",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - An electron spin resonance study of fremy's salt in a dilute polycrystalline environment

AU - Jones, M. T.

AU - Trugman, Stuart Alan

AU - Rapini, V.

AU - Hameed, R.

PY - 1977/1/1

Y1 - 1977/1/1

N2 - The ESR spectrum of Fremy's salt, (KSO3)2NO, in a dilute polycrystalline matrix has been recorded. The matrix used is the usual diamagnetic, yellow-orange form of Fremy's salt. The spectrum has been analyzed and the anisotropic magnetic resonance parameters which describe it have been measured. The value of the parameters so obtained are as follows: g1 = 2.00832 (±0.00002); g2 = 2.00589 (±0.00005); g3 = 2.00259 (±0.00005); A1 = 5.5 (±0.1); A2 = 5.5 (±0.1); A3 = 28.9 (±0.2). Not surprisingly, it is found that these parameters depend upon the matrix in which the Fremy's salt is found.

AB - The ESR spectrum of Fremy's salt, (KSO3)2NO, in a dilute polycrystalline matrix has been recorded. The matrix used is the usual diamagnetic, yellow-orange form of Fremy's salt. The spectrum has been analyzed and the anisotropic magnetic resonance parameters which describe it have been measured. The value of the parameters so obtained are as follows: g1 = 2.00832 (±0.00002); g2 = 2.00589 (±0.00005); g3 = 2.00259 (±0.00005); A1 = 5.5 (±0.1); A2 = 5.5 (±0.1); A3 = 28.9 (±0.2). Not surprisingly, it is found that these parameters depend upon the matrix in which the Fremy's salt is found.

UR - https://www.scopus.com/pages/publications/33847090433

U2 - 10.1021/j100522a015

DO - 10.1021/j100522a015

M3 - Article

SN - 0022-3654

VL - 81

SP - 664

EP - 665

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 7

ER -

An electron spin resonance study of fremy's salt in a dilute polycrystalline environment

Abstract

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