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Dissolution of NiFe<inf>2</inf>O<inf>4</inf> particles in a NiO matrix

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Abstract

A TEM sample containing NiFe2O4 particles in a NiO matrix was subjected to a series of heat treatments in air and then characterized between heat treatments. Spinel particles between 75 and 100 nm in size were observed after a 1000°C heat treatment but had disappeared after a 1015°C heat treatment. According to the NiFeO phase diagram, a TEM sample containing 4 cation-% Fe should contain spinel particles up to 1200°C. This discrepancy between the experimentally observed temperature at which spinel dissolved and the temperature predicted by the phase diagram is discussed in terms of the Gibbs-Thomson effect. © 1992.
Original languageEnglish
Pages (from-to)2799-2804
Number of pages6
JournalActa Metallurgica Et Materialia
Volume40
Issue number10
DOIs
StatePublished - Jan 1 1992
Externally publishedYes

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