Abstract
A TEM sample containing NiFe2O4 particles in a NiO matrix was subjected to a series of heat treatments in air and then characterized between heat treatments. Spinel particles between 75 and 100 nm in size were observed after a 1000°C heat treatment but had disappeared after a 1015°C heat treatment. According to the NiFeO phase diagram, a TEM sample containing 4 cation-% Fe should contain spinel particles up to 1200°C. This discrepancy between the experimentally observed temperature at which spinel dissolved and the temperature predicted by the phase diagram is discussed in terms of the Gibbs-Thomson effect. © 1992.
| Original language | English |
|---|---|
| Pages (from-to) | 2799-2804 |
| Number of pages | 6 |
| Journal | Acta Metallurgica Et Materialia |
| Volume | 40 |
| Issue number | 10 |
| DOIs | |
| State | Published - Jan 1 1992 |
| Externally published | Yes |
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