Evidence of dynamical effects and critical field in a cobalt spin crossover complex

Thilini K. Ekanayaka, Ping Wang, Saeed Yazdani, Jared Paul Phillips, Esha Mishra, Ashley S. Dale, Alpha T. N'Diaye, Christoph Klewe, Padraic Shafer, John Freeland, Robert Streubel, James Paris Wampler, Vivien Zapf, Ruihua Cheng, Michael Shatruk, Peter A. Dowben

Research output: Contribution to journalArticlepeer-review

5 Scopus citations

Abstract

The [Co(SQ)2(4-CN-py)2] complex exhibits dynamical effects over a wide range of temperature. The orbital moment, determined by X-ray magnetic circular dichroism (XMCD) with decreasing applied magnetic field, indicates a nonzero critical field for net alignment of magnetic moments, an effect not seen with the spin moment of [Co(SQ)2(4-CN-py)2]. This journal is

Original languageEnglish
Pages (from-to)661-664
Number of pages4
JournalChemical Communications
Volume58
Issue number5
DOIs
StatePublished - Jan 16 2022

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