Femtosecond vibrational relaxation of large organic molecules

Antoinette Jane Taylor; D. J. Erskine; C. L. Tang

doi:10.1016/0009-2614(84)80334-6

Femtosecond vibrational relaxation of large organic molecules

Antoinette Jane Taylor
, D. J. Erskine
, C. L. Tang

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

The intramolecular relaxation time of highly excited states of the vibronic manifold of the first excited singlet state of large organic molecules such as Nile Blue, Rhodamine 640, DODC iodide, Cresyl Violet, and Oxazine 725 in solution is shown to be extremely fast, less than 30 fs. We believe that this is a characteristic time of the relaxation due to anharmonic coupling among the many degrees of freedom of the molecule.

Original language	English
Pages (from-to)	430-435
Number of pages	6
Journal	Chemical Physics Letters
Volume	103
Issue number	5
DOIs	https://doi.org/10.1016/0009-2614(84)80334-6
State	Published - Jan 13 1984
Externally published	Yes

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title = "Femtosecond vibrational relaxation of large organic molecules",

abstract = "The intramolecular relaxation time of highly excited states of the vibronic manifold of the first excited singlet state of large organic molecules such as Nile Blue, Rhodamine 640, DODC iodide, Cresyl Violet, and Oxazine 725 in solution is shown to be extremely fast, less than 30 fs. We believe that this is a characteristic time of the relaxation due to anharmonic coupling among the many degrees of freedom of the molecule.",

author = "Taylor, \{Antoinette Jane\} and Erskine, \{D. J.\} and Tang, \{C. L.\}",

year = "1984",

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doi = "10.1016/0009-2614(84)80334-6",

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journal = "Chemical Physics Letters",

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T1 - Femtosecond vibrational relaxation of large organic molecules

AU - Taylor, Antoinette Jane

AU - Erskine, D. J.

AU - Tang, C. L.

PY - 1984/1/13

Y1 - 1984/1/13

N2 - The intramolecular relaxation time of highly excited states of the vibronic manifold of the first excited singlet state of large organic molecules such as Nile Blue, Rhodamine 640, DODC iodide, Cresyl Violet, and Oxazine 725 in solution is shown to be extremely fast, less than 30 fs. We believe that this is a characteristic time of the relaxation due to anharmonic coupling among the many degrees of freedom of the molecule.

AB - The intramolecular relaxation time of highly excited states of the vibronic manifold of the first excited singlet state of large organic molecules such as Nile Blue, Rhodamine 640, DODC iodide, Cresyl Violet, and Oxazine 725 in solution is shown to be extremely fast, less than 30 fs. We believe that this is a characteristic time of the relaxation due to anharmonic coupling among the many degrees of freedom of the molecule.

UR - https://www.scopus.com/pages/publications/0001494173

U2 - 10.1016/0009-2614(84)80334-6

DO - 10.1016/0009-2614(84)80334-6

M3 - Article

SN - 0009-2614

VL - 103

SP - 430

EP - 435

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 5

ER -

Femtosecond vibrational relaxation of large organic molecules

Abstract

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