Heteroleptic complexes of terbium(III) phenylanthranilate (Tb(PA) 3) with triphenylphosphine oxide (TPPO): A Tb(PA)3(TPPO) 2-based electroluminescent device

S. V. Eliseeva; O. V. Mirzov; L. S. Lepnev; R. A. Ivanov; R. V. Nichiporuk; Sergei A Ivanov; M. Vestling; N. P. Kuz'mina

Heteroleptic complexes of terbium(III) phenylanthranilate (Tb(PA) ₃) with triphenylphosphine oxide (TPPO): A Tb(PA)₃(TPPO) ₂-based electroluminescent device

S. V. Eliseeva
, O. V. Mirzov
, L. S. Lepnev
, R. A. Ivanov
, R. V. Nichiporuk
, Sergei A Ivanov
, M. Vestling
, N. P. Kuz'mina

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

Heteroleptic complexes of terbium(III) phenylanthranilate with triphenylphosphine oxide of composition Tb(PA)₃(TPPO)_n (n = 1 or 2) were synthesized and characterized by elemental analysis, IR and photoluminescence spectroscopy, and thermal analysis. The structures of Tb(PA)₃(TPPO)₂ and Tb(PA)₃(Phen) in solution were studied by the MALDITOF-MS method. The photoluminescence properties of the terbium(III) complex with phenylanthranilic acid were compared with those of the terbium(III) complex with salicylic acid (o-hydroxybenzoic acid, HSal). An electroluminescent device with the structure ITO/PEDOT : PSS/PVC/Tb(PA) ₃(TPPO)₂/Al was constructed. The possibility of using heteroleptic aromatic carboxylates as emission layers for the construction of electroluminescent devices was exemplified by the Tb(PA)₃(TPPO) ₂ complex.

Original language	English
Pages (from-to)	534-540
Number of pages	7
Journal	Russian Journal of Inorganic Chemistry
Volume	50
Issue number	4
State	Published - Apr 2005
Externally published	Yes

Cite this

@article{b9f9d018bb154eefb089b07de963cdfe,

title = "Heteroleptic complexes of terbium(III) phenylanthranilate (Tb(PA) 3) with triphenylphosphine oxide (TPPO): A Tb(PA)3(TPPO) 2-based electroluminescent device",

abstract = "Heteroleptic complexes of terbium(III) phenylanthranilate with triphenylphosphine oxide of composition Tb(PA)3(TPPO)n (n = 1 or 2) were synthesized and characterized by elemental analysis, IR and photoluminescence spectroscopy, and thermal analysis. The structures of Tb(PA)3(TPPO)2 and Tb(PA)3(Phen) in solution were studied by the MALDITOF-MS method. The photoluminescence properties of the terbium(III) complex with phenylanthranilic acid were compared with those of the terbium(III) complex with salicylic acid (o-hydroxybenzoic acid, HSal). An electroluminescent device with the structure ITO/PEDOT : PSS/PVC/Tb(PA) 3(TPPO)2/Al was constructed. The possibility of using heteroleptic aromatic carboxylates as emission layers for the construction of electroluminescent devices was exemplified by the Tb(PA)3(TPPO) 2 complex.",

author = "Eliseeva, \{S. V.\} and Mirzov, \{O. V.\} and Lepnev, \{L. S.\} and Ivanov, \{R. A.\} and Nichiporuk, \{R. V.\} and Ivanov, \{Sergei A\} and M. Vestling and Kuz'mina, \{N. P.\}",

year = "2005",

month = apr,

language = "English",

volume = "50",

pages = "534--540",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "Pleiades Publishing",

number = "4",

}

TY - JOUR

T1 - Heteroleptic complexes of terbium(III) phenylanthranilate (Tb(PA) 3) with triphenylphosphine oxide (TPPO)

T2 - A Tb(PA)3(TPPO) 2-based electroluminescent device

AU - Eliseeva, S. V.

AU - Mirzov, O. V.

AU - Lepnev, L. S.

AU - Ivanov, R. A.

AU - Nichiporuk, R. V.

AU - Ivanov, Sergei A

AU - Vestling, M.

AU - Kuz'mina, N. P.

PY - 2005/4

Y1 - 2005/4

N2 - Heteroleptic complexes of terbium(III) phenylanthranilate with triphenylphosphine oxide of composition Tb(PA)3(TPPO)n (n = 1 or 2) were synthesized and characterized by elemental analysis, IR and photoluminescence spectroscopy, and thermal analysis. The structures of Tb(PA)3(TPPO)2 and Tb(PA)3(Phen) in solution were studied by the MALDITOF-MS method. The photoluminescence properties of the terbium(III) complex with phenylanthranilic acid were compared with those of the terbium(III) complex with salicylic acid (o-hydroxybenzoic acid, HSal). An electroluminescent device with the structure ITO/PEDOT : PSS/PVC/Tb(PA) 3(TPPO)2/Al was constructed. The possibility of using heteroleptic aromatic carboxylates as emission layers for the construction of electroluminescent devices was exemplified by the Tb(PA)3(TPPO) 2 complex.

AB - Heteroleptic complexes of terbium(III) phenylanthranilate with triphenylphosphine oxide of composition Tb(PA)3(TPPO)n (n = 1 or 2) were synthesized and characterized by elemental analysis, IR and photoluminescence spectroscopy, and thermal analysis. The structures of Tb(PA)3(TPPO)2 and Tb(PA)3(Phen) in solution were studied by the MALDITOF-MS method. The photoluminescence properties of the terbium(III) complex with phenylanthranilic acid were compared with those of the terbium(III) complex with salicylic acid (o-hydroxybenzoic acid, HSal). An electroluminescent device with the structure ITO/PEDOT : PSS/PVC/Tb(PA) 3(TPPO)2/Al was constructed. The possibility of using heteroleptic aromatic carboxylates as emission layers for the construction of electroluminescent devices was exemplified by the Tb(PA)3(TPPO) 2 complex.

UR - https://www.scopus.com/pages/publications/20944436042

M3 - Article

SN - 0036-0236

VL - 50

SP - 534

EP - 540

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 4

ER -

Heteroleptic complexes of terbium(III) phenylanthranilate (Tb(PA) 3) with triphenylphosphine oxide (TPPO): A Tb(PA)3(TPPO) 2-based electroluminescent device

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Heteroleptic complexes of terbium(III) phenylanthranilate (Tb(PA) ₃) with triphenylphosphine oxide (TPPO): A Tb(PA)₃(TPPO) ₂-based electroluminescent device