Abstract
The lattice effects on the magnetic and transport properties in La 0.67-xGdxSr0.33CoO3 series are studied. The introduction of smaller Gd3+ ions leads to an enhanced mismatch between the La-O layer and the CoO2 layer and a decrease of the tolerance factor t. The spin-state of trivalent Co ion transits to low-spin state with the decrease of Co-O bond length. The doping of Gd3+ drives the system from the cluster-glass state to the spin-glass state and progressively decreases the Curie temperature. At high Gd3+ doping content, an interesting negative magnetoresistance occurs at low temperature.
| Original language | English |
|---|---|
| Title of host publication | Proceedings of SPIE the International Society for Optical Engineering |
| Pages | 1-9 |
| Number of pages | 9 |
| Volume | 5932 |
| DOIs | |
| State | Published - Dec 1 2005 |
| Externally published | Yes |
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