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Mapping the composition-dependence of the energy bandgap of GaAsNBi alloys

  • J. Occena
  • , T. Jen
  • , J. W. Mitchell
  • , W. M. Linhart
  • , E. M. Pavelescu
  • , R. Kudrawiec
  • , Y. Q. Wang
  • , R. S. Goldman

Research output: Contribution to journalArticlepeer-review

11 Scopus citations

Abstract

We have examined the alloy composition dependence of the energy bandgap and electronic states in GaAsNBi alloys. Using direct measurements of N and Bi mole fractions, via ion beam analysis, in conjunction with direct measurements of the out-of-plane misfit via x-ray rocking curves, we determine the "magic ratio" for lattice-matching of GaAsNBi alloys with GaAs substrates. In addition, using a combination of photoreflectance and photoluminescence spectroscopy, we map the composition- and misfit-dependence of the energy bandgaps, along with revealing the energetic position of Bi-related states at approximately 0.18 eV above the valence band maximum.

Original languageEnglish
Article number082106
JournalApplied Physics Letters
Volume115
Issue number8
DOIs
StatePublished - Aug 19 2019

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