Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45-(PEt3)16] clusters based on a hypothetical Pd38 vertex-truncated ν3 octahedron

Evgueni G. Mednikov; Sergei A Ivanov; Irina V. Slovokhotova; Lawrence F. Dahl

doi:10.1002/anie.200502307

Nanosized [Pd₅₂(CO)₃₆(PEt₃)₁₄] and [Pd₆₆(CO)₄₅-(PEt₃)₁₆] clusters based on a hypothetical Pd₃₈ vertex-truncated ν₃ octahedron

Evgueni G. Mednikov
, Sergei A Ivanov
, Irina V. Slovokhotova
, Lawrence F. Dahl

Research output: Contribution to journal › Article › peer-review

26 Scopus citations

Abstract

Room for one more? The structures of nanosized Pd₅₂ and Pd ₆₆ clusters that are based upon a common Pd₃₈ vertex-truncated ν-octahedral kernel have been determined. The 45 CO ligands in the Pd₆₆ cluster (see core structure), [Pd₆₆(CO) ₄₅-(PEt₃)₁₆], are described in terms of one extra and 44 normal ligands, two of which undergo rearrangement to accommodate the 45th CO ligand without causing any substantial changes to the architecture of the metal core. (Figure Presented)

Original language	English
Pages (from-to)	6848-6854
Number of pages	7
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	42
DOIs	https://doi.org/10.1002/anie.200502307
State	Published - Oct 28 2005
Externally published	Yes

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title = "Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45-(PEt3)16] clusters based on a hypothetical Pd38 vertex-truncated ν3 octahedron",

abstract = "Room for one more? The structures of nanosized Pd52 and Pd 66 clusters that are based upon a common Pd38 vertex-truncated ν-octahedral kernel have been determined. The 45 CO ligands in the Pd66 cluster (see core structure), [Pd66(CO) 45-(PEt3)16], are described in terms of one extra and 44 normal ligands, two of which undergo rearrangement to accommodate the 45th CO ligand without causing any substantial changes to the architecture of the metal core. (Figure Presented)",

author = "Mednikov, \{Evgueni G.\} and Ivanov, \{Sergei A\} and Slovokhotova, \{Irina V.\} and Dahl, \{Lawrence F.\}",

year = "2005",

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doi = "10.1002/anie.200502307",

language = "English",

volume = "44",

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journal = "Angewandte Chemie - International Edition",

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T1 - Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45-(PEt3)16] clusters based on a hypothetical Pd38 vertex-truncated ν3 octahedron

AU - Mednikov, Evgueni G.

AU - Ivanov, Sergei A

AU - Slovokhotova, Irina V.

AU - Dahl, Lawrence F.

PY - 2005/10/28

Y1 - 2005/10/28

N2 - Room for one more? The structures of nanosized Pd52 and Pd 66 clusters that are based upon a common Pd38 vertex-truncated ν-octahedral kernel have been determined. The 45 CO ligands in the Pd66 cluster (see core structure), [Pd66(CO) 45-(PEt3)16], are described in terms of one extra and 44 normal ligands, two of which undergo rearrangement to accommodate the 45th CO ligand without causing any substantial changes to the architecture of the metal core. (Figure Presented)

AB - Room for one more? The structures of nanosized Pd52 and Pd 66 clusters that are based upon a common Pd38 vertex-truncated ν-octahedral kernel have been determined. The 45 CO ligands in the Pd66 cluster (see core structure), [Pd66(CO) 45-(PEt3)16], are described in terms of one extra and 44 normal ligands, two of which undergo rearrangement to accommodate the 45th CO ligand without causing any substantial changes to the architecture of the metal core. (Figure Presented)

UR - https://www.scopus.com/pages/publications/27544478678

U2 - 10.1002/anie.200502307

DO - 10.1002/anie.200502307

M3 - Article

SN - 1433-7851

VL - 44

SP - 6848

EP - 6854

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 42

ER -

Nanosized [Pd52(CO)36(PEt3)14] and [Pd66(CO)45-(PEt3)16] clusters based on a hypothetical Pd38 vertex-truncated ν3 octahedron

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Nanosized [Pd₅₂(CO)₃₆(PEt₃)₁₄] and [Pd₆₆(CO)₄₅-(PEt₃)₁₆] clusters based on a hypothetical Pd₃₈ vertex-truncated ν₃ octahedron