Neutron diffraction study of cyanate ligand order/disorder in AgNCO at 300-50 K

D. J. Williams; S. C. Vogel; L. L. Daemen

doi:10.1016/j.physb.2006.05.197

Neutron diffraction study of cyanate ligand order/disorder in AgNCO at 300-50 K

D. J. Williams
, S. C. Vogel
, L. L. Daemen

Los Alamos National Laboratory

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

The study of ordered/disordered cyanate ligands in AgNCO was carried out using the neutron powder diffractometers, high-pressure preferred orientation (HIPPO) and high-intensity powder diffractometer (HIPD), at LANSCE. Structural analysis was performed on AgNCO at five different temperatures (300, 200, 150, 100 and 50 K). AgNCO (No. 11, P2₁/m, a = 5.4742 (3) Å, b = 6.3784 (2) Å, c = 3.4170 (1) Åβ = 90.931 (5), vol.=119.298(8), density=4.173 g/cm³, and Z = 2) was found to have an ordered OCN ligand from 300 to 50 K. The bond lengths results from the analysis yielded Ag-N=2.1483(14) Å, C-N=1.1708(33) Å and C-O=1.1829(35) Å.

Original language	English
Pages (from-to)	228-230
Number of pages	3
Journal	Physica B: Physics of Condensed Matter
Volume	385-386 I
DOIs	https://doi.org/10.1016/j.physb.2006.05.197
State	Published - Nov 27 2006

Access to Document

10.1016/j.physb.2006.05.197

Cite this

@article{3a9c541bcbed43519d88d562915ab260,

title = "Neutron diffraction study of cyanate ligand order/disorder in AgNCO at 300-50 K",

abstract = "The study of ordered/disordered cyanate ligands in AgNCO was carried out using the neutron powder diffractometers, high-pressure preferred orientation (HIPPO) and high-intensity powder diffractometer (HIPD), at LANSCE. Structural analysis was performed on AgNCO at five different temperatures (300, 200, 150, 100 and 50 K). AgNCO (No. 11, P21/m, a = 5.4742 (3) {\AA}, b = 6.3784 (2) {\AA}, c = 3.4170 (1) {\AA}β = 90.931 (5), vol.=119.298(8), density=4.173 g/cm3, and Z = 2) was found to have an ordered OCN ligand from 300 to 50 K. The bond lengths results from the analysis yielded Ag-N=2.1483(14) {\AA}, C-N=1.1708(33) {\AA} and C-O=1.1829(35) {\AA}.",

author = "Williams, \{D. J.\} and Vogel, \{S. C.\} and Daemen, \{L. L.\}",

year = "2006",

month = nov,

day = "27",

doi = "10.1016/j.physb.2006.05.197",

language = "English",

volume = "385-386 I",

pages = "228--230",

journal = "Physica B: Physics of Condensed Matter",

issn = "0921-4526",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Neutron diffraction study of cyanate ligand order/disorder in AgNCO at 300-50 K

AU - Williams, D. J.

AU - Vogel, S. C.

AU - Daemen, L. L.

PY - 2006/11/27

Y1 - 2006/11/27

N2 - The study of ordered/disordered cyanate ligands in AgNCO was carried out using the neutron powder diffractometers, high-pressure preferred orientation (HIPPO) and high-intensity powder diffractometer (HIPD), at LANSCE. Structural analysis was performed on AgNCO at five different temperatures (300, 200, 150, 100 and 50 K). AgNCO (No. 11, P21/m, a = 5.4742 (3) Å, b = 6.3784 (2) Å, c = 3.4170 (1) Åβ = 90.931 (5), vol.=119.298(8), density=4.173 g/cm3, and Z = 2) was found to have an ordered OCN ligand from 300 to 50 K. The bond lengths results from the analysis yielded Ag-N=2.1483(14) Å, C-N=1.1708(33) Å and C-O=1.1829(35) Å.

AB - The study of ordered/disordered cyanate ligands in AgNCO was carried out using the neutron powder diffractometers, high-pressure preferred orientation (HIPPO) and high-intensity powder diffractometer (HIPD), at LANSCE. Structural analysis was performed on AgNCO at five different temperatures (300, 200, 150, 100 and 50 K). AgNCO (No. 11, P21/m, a = 5.4742 (3) Å, b = 6.3784 (2) Å, c = 3.4170 (1) Åβ = 90.931 (5), vol.=119.298(8), density=4.173 g/cm3, and Z = 2) was found to have an ordered OCN ligand from 300 to 50 K. The bond lengths results from the analysis yielded Ag-N=2.1483(14) Å, C-N=1.1708(33) Å and C-O=1.1829(35) Å.

UR - https://www.scopus.com/pages/publications/33751310848

U2 - 10.1016/j.physb.2006.05.197

DO - 10.1016/j.physb.2006.05.197

M3 - Article

SN - 0921-4526

VL - 385-386 I

SP - 228

EP - 230

JO - Physica B: Physics of Condensed Matter

JF - Physica B: Physics of Condensed Matter

ER -

Neutron diffraction study of cyanate ligand order/disorder in AgNCO at 300-50 K

Abstract

Access to Document

Fingerprint

Cite this