Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex

D. Dawson Beattie; Eric G. Bowes; Marcus W. Drover; Jennifer A. Love; Laurel L. Schafer

doi:10.1002/anie.201607243

Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex

D. Dawson Beattie
, Eric G. Bowes
, Marcus W. Drover
, Jennifer A. Love
, Laurel L. Schafer

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Amidate-supported two- and three-coordinate NiIcomplexes were synthesized by reduction of the corresponding NiIIprecursors. A dramatic change in binding mode is observed upon reduction from NiIIto NiI. The NiIderivatives include an unprecedented NiIbis(C−H) agostic complex and a two-coordinate NiIcomplex.

Original language	English
Pages (from-to)	13290-13295
Number of pages	6
Journal	Angewandte Chemie - International Edition
Volume	55
Issue number	42
DOIs	https://doi.org/10.1002/anie.201607243
State	Published - Oct 10 2016
Externally published	Yes

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10.1002/anie.201607243

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title = "Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex",

abstract = "Amidate-supported two- and three-coordinate NiIcomplexes were synthesized by reduction of the corresponding NiIIprecursors. A dramatic change in binding mode is observed upon reduction from NiIIto NiI. The NiIderivatives include an unprecedented NiIbis(C−H) agostic complex and a two-coordinate NiIcomplex.",

author = "Beattie, \{D. Dawson\} and Bowes, \{Eric G.\} and Drover, \{Marcus W.\} and Love, \{Jennifer A.\} and Schafer, \{Laurel L.\}",

year = "2016",

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doi = "10.1002/anie.201607243",

language = "English",

volume = "55",

pages = "13290--13295",

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T1 - Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex

AU - Beattie, D. Dawson

AU - Bowes, Eric G.

AU - Drover, Marcus W.

AU - Love, Jennifer A.

AU - Schafer, Laurel L.

PY - 2016/10/10

Y1 - 2016/10/10

N2 - Amidate-supported two- and three-coordinate NiIcomplexes were synthesized by reduction of the corresponding NiIIprecursors. A dramatic change in binding mode is observed upon reduction from NiIIto NiI. The NiIderivatives include an unprecedented NiIbis(C−H) agostic complex and a two-coordinate NiIcomplex.

AB - Amidate-supported two- and three-coordinate NiIcomplexes were synthesized by reduction of the corresponding NiIIprecursors. A dramatic change in binding mode is observed upon reduction from NiIIto NiI. The NiIderivatives include an unprecedented NiIbis(C−H) agostic complex and a two-coordinate NiIcomplex.

UR - https://www.scopus.com/pages/publications/84988422480

U2 - 10.1002/anie.201607243

DO - 10.1002/anie.201607243

M3 - Article

SN - 1433-7851

VL - 55

SP - 13290

EP - 13295

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 42

ER -

Oxidation State Dependent Coordination Modes: Accessing an Amidate-Supported Nickel(I) δ-bis(C−H) Agostic Complex

Abstract

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