Abstract
We prepared YBa2Cu3 powder by ball milling a 2:1 molar mixture of the intermetallics BaCu and CuY. We synthesized YBa2Cu3(16O)7-x and YBa2Cu3(18O)7-x by oxidizing the YBa2Cu3 powder in O16 and O18. The O16/18O ratios were determined by laser-ionization and sputtering-ionization mass spectroscopy. The YBa2Cu3(160)7-x sample had 99.8 at. %16O, and the YBa2Cu3(18O)7-x sample had 96.5 at. %18O. Susceptibility measurements of the superconducting transition temperature (Tc=91.7 K for O16; half-point transition at 84 K show an isotope effect of 0.40.1 K. © 1989 The American Physical Society.
| Original language | English |
|---|---|
| Pages (from-to) | 6690-6693 |
| Number of pages | 4 |
| Journal | Physical Review B - Condensed Matter and Materials Physics |
| Volume | 39 |
| Issue number | 10 |
| DOIs | |
| State | Published - Jan 1 1989 |
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