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Oxygen isotope effect in YBa2Cu3O7 prepared by burning YBa2Cu3 in O16 and O18

  • Pascal J. Yvon
  • , R. B. Schwarz
  • , C. B. Pierce
  • , L. Bernardez
  • , A. Conners
  • , R. Meisenheimer

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

We prepared YBa2Cu3 powder by ball milling a 2:1 molar mixture of the intermetallics BaCu and CuY. We synthesized YBa2Cu3(16O)7-x and YBa2Cu3(18O)7-x by oxidizing the YBa2Cu3 powder in O16 and O18. The O16/18O ratios were determined by laser-ionization and sputtering-ionization mass spectroscopy. The YBa2Cu3(160)7-x sample had 99.8 at. %16O, and the YBa2Cu3(18O)7-x sample had 96.5 at. %18O. Susceptibility measurements of the superconducting transition temperature (Tc=91.7 K for O16; half-point transition at 84 K show an isotope effect of 0.40.1 K. © 1989 The American Physical Society.
Original languageEnglish
Pages (from-to)6690-6693
Number of pages4
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume39
Issue number10
DOIs
StatePublished - Jan 1 1989

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