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Palladium salicylaldimine complexes derived from 2,3-dihydroxybenzaldehyde

  • Eric G. Bowes
  • , Graham M. Lee
  • , Christopher M. Vogels
  • , Andreas Decken
  • , Stephen A. Westcott

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

Schiff bases derived from condensation of 2,3-dihydroxybenzaldehyde with various primary amines, such as 1-adamantanamine hydrochloride, 2,6-dimethylaniline, 2,6-diethylaniline and 2,6-diisopropylaniline, react with palladium(II) acetate to give the corresponding bis(N-arylsalicylaldiminato) palladium(II) complexes. These complexes have been found to be active catalyst precursors for the Suzuki-Miyaura cross-coupling of aryl bromides and iodides with aryl boronic acids using water as a solvent. © 2011 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)84-90
Number of pages7
JournalInorganica Chimica Acta
Volume377
Issue number1
DOIs
StatePublished - Nov 1 2011
Externally publishedYes

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