[Pd30(CO)26(PEt3)10] and [Pd54(CO)40(PEt3)14]: Generation of nanosized Pd30- and Pd54-core geometries containing interpenetrating cuboctahedral-based metal polyhedra

Eugeny G. Mednikov; Sergei A Ivanov; Lawrence F. Dahl

doi:10.1002/anie.200390107

[Pd₃₀(CO)₂₆(PEt₃)₁₀] and [Pd₅₄(CO)₄₀(PEt₃)₁₄]: Generation of nanosized Pd₃₀- and Pd₅₄-core geometries containing interpenetrating cuboctahedral-based metal polyhedra

Eugeny G. Mednikov
, Sergei A Ivanov
, Lawrence F. Dahl

Research output: Contribution to journal › Article › peer-review

44 Scopus citations

Abstract

Unprecedented metal-core architectures are exhibited by the title palladium cluster compounds, the structures of which consist of twinned cuboctahedral units. The Pd₃₀ core (see picture) consists of two Pd₁₃ fragments that form a Pd₂₀ bicuboctahedron (blue) with six common atoms, in addition to six face-capping (orange) and four wingtip (green) Pd atoms. The Pd₅₄ core is a more complex, five-layered supracluster, but contains the same central Pd₂₀ bicuboctahedron as observed in the Pd₃₀ cluster.

Original language	English
Pages (from-to)	323-327
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	42
Issue number	3
DOIs	https://doi.org/10.1002/anie.200390107
State	Published - Jan 20 2003
Externally published	Yes

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10.1002/anie.200390107

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@article{cec9e600f9824500810a51aa18ead296,

title = "[Pd30(CO)26(PEt3)10] and [Pd54(CO)40(PEt3)14]: Generation of nanosized Pd30- and Pd54-core geometries containing interpenetrating cuboctahedral-based metal polyhedra",

abstract = "Unprecedented metal-core architectures are exhibited by the title palladium cluster compounds, the structures of which consist of twinned cuboctahedral units. The Pd30 core (see picture) consists of two Pd13 fragments that form a Pd20 bicuboctahedron (blue) with six common atoms, in addition to six face-capping (orange) and four wingtip (green) Pd atoms. The Pd54 core is a more complex, five-layered supracluster, but contains the same central Pd20 bicuboctahedron as observed in the Pd30 cluster.",

author = "Mednikov, \{Eugeny G.\} and Ivanov, \{Sergei A\} and Dahl, \{Lawrence F.\}",

year = "2003",

month = jan,

day = "20",

doi = "10.1002/anie.200390107",

language = "English",

volume = "42",

pages = "323--327",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "3",

}

[Pd₃₀(CO)₂₆(PEt₃)₁₀] and [Pd₅₄(CO)₄₀(PEt₃)₁₄]: Generation of nanosized Pd₃₀- and Pd₅₄-core geometries containing interpenetrating cuboctahedral-based metal polyhedra. / Mednikov, Eugeny G.; Ivanov, Sergei A; Dahl, Lawrence F.
In: Angewandte Chemie - International Edition, Vol. 42, No. 3, 20.01.2003, p. 323-327.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [Pd30(CO)26(PEt3)10] and [Pd54(CO)40(PEt3)14]

T2 - Generation of nanosized Pd30- and Pd54-core geometries containing interpenetrating cuboctahedral-based metal polyhedra

AU - Mednikov, Eugeny G.

AU - Ivanov, Sergei A

AU - Dahl, Lawrence F.

PY - 2003/1/20

Y1 - 2003/1/20

N2 - Unprecedented metal-core architectures are exhibited by the title palladium cluster compounds, the structures of which consist of twinned cuboctahedral units. The Pd30 core (see picture) consists of two Pd13 fragments that form a Pd20 bicuboctahedron (blue) with six common atoms, in addition to six face-capping (orange) and four wingtip (green) Pd atoms. The Pd54 core is a more complex, five-layered supracluster, but contains the same central Pd20 bicuboctahedron as observed in the Pd30 cluster.

AB - Unprecedented metal-core architectures are exhibited by the title palladium cluster compounds, the structures of which consist of twinned cuboctahedral units. The Pd30 core (see picture) consists of two Pd13 fragments that form a Pd20 bicuboctahedron (blue) with six common atoms, in addition to six face-capping (orange) and four wingtip (green) Pd atoms. The Pd54 core is a more complex, five-layered supracluster, but contains the same central Pd20 bicuboctahedron as observed in the Pd30 cluster.

UR - https://www.scopus.com/pages/publications/0037455260

U2 - 10.1002/anie.200390107

DO - 10.1002/anie.200390107

M3 - Article

SN - 1433-7851

VL - 42

SP - 323

EP - 327

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 3

ER -

[Pd30(CO)26(PEt3)10] and [Pd54(CO)40(PEt3)14]: Generation of nanosized Pd30- and Pd54-core geometries containing interpenetrating cuboctahedral-based metal polyhedra

Abstract

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[Pd₃₀(CO)₂₆(PEt₃)₁₀] and [Pd₅₄(CO)₄₀(PEt₃)₁₄]: Generation of nanosized Pd₃₀- and Pd₅₄-core geometries containing interpenetrating cuboctahedral-based metal polyhedra