Picosecond infrared study of ultrafast electron transfer and vibrational energy relaxation in [(NC)5RUIICNRuIII (NH3)3]1-

P. O. Stoutland; Stephen K Doorn; R. B. Dyer; W. H. Woodruff

Picosecond infrared study of ultrafast electron transfer and vibrational energy relaxation in [(NC)5RUIICNRuIII (NH3)3]1-

P. O. Stoutland
, Stephen K Doorn
, R. B. Dyer
, W. H. Woodruff

Los Alamos National Laboratory

Research output: Chapter in Book/Report/Conference proceeding › Chapter

Abstract

The dynamics of [(NC)₅Ru^IICNRu^III(NH₃)₅ ]^1- following MMCT optical excitation with the use of picosecond infrared spectroscopy. We monitor the terminal RuC ≡ N stretching vibrational frequency which is sensitive to the oxidation state of the ruthenium cyanide centre and, because of anharmonicity, to the degree of vibrational excitation of this mode.

Original language	English
Title of host publication	Ultrafast Phenomena VIII
Publisher	Unknown Publisher
Pages	579-581
Number of pages	3
Edition	55
ISBN (Print)	3540564756
State	Published - Jan 1 1993
Event	Proceedings of the 8th International Conference on Ultrafast Phenomena - Duration: Jan 1 1993 → …

Conference

Conference	Proceedings of the 8th International Conference on Ultrafast Phenomena
Period	01/1/93 → …

Cite this

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title = "Picosecond infrared study of ultrafast electron transfer and vibrational energy relaxation in [(NC)5RUIICNRuIII (NH3)3]1-",

abstract = "The dynamics of [(NC)5RuIICNRuIII(NH3)5 ]1- following MMCT optical excitation with the use of picosecond infrared spectroscopy. We monitor the terminal RuC ≡ N stretching vibrational frequency which is sensitive to the oxidation state of the ruthenium cyanide centre and, because of anharmonicity, to the degree of vibrational excitation of this mode.",

author = "Stoutland, \{P. O.\} and Doorn, \{Stephen K\} and Dyer, \{R. B.\} and Woodruff, \{W. H.\}",

year = "1993",

month = jan,

day = "1",

language = "English",

isbn = "3540564756",

pages = "579--581",

booktitle = "Ultrafast Phenomena VIII",

publisher = "Unknown Publisher",

edition = "55",

note = "Proceedings of the 8th International Conference on Ultrafast Phenomena ; Conference date: 01-01-1993",

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TY - CHAP

T1 - Picosecond infrared study of ultrafast electron transfer and vibrational energy relaxation in [(NC)5RUIICNRuIII (NH3)3]1-

AU - Stoutland, P. O.

AU - Doorn, Stephen K

AU - Dyer, R. B.

AU - Woodruff, W. H.

PY - 1993/1/1

Y1 - 1993/1/1

N2 - The dynamics of [(NC)5RuIICNRuIII(NH3)5 ]1- following MMCT optical excitation with the use of picosecond infrared spectroscopy. We monitor the terminal RuC ≡ N stretching vibrational frequency which is sensitive to the oxidation state of the ruthenium cyanide centre and, because of anharmonicity, to the degree of vibrational excitation of this mode.

AB - The dynamics of [(NC)5RuIICNRuIII(NH3)5 ]1- following MMCT optical excitation with the use of picosecond infrared spectroscopy. We monitor the terminal RuC ≡ N stretching vibrational frequency which is sensitive to the oxidation state of the ruthenium cyanide centre and, because of anharmonicity, to the degree of vibrational excitation of this mode.

UR - https://www.scopus.com/pages/publications/0027866058

M3 - Chapter

SN - 3540564756

SP - 579

EP - 581

BT - Ultrafast Phenomena VIII

PB - Unknown Publisher

T2 - Proceedings of the 8th International Conference on Ultrafast Phenomena

Y2 - 1 January 1993

ER -

Picosecond infrared study of ultrafast electron transfer and vibrational energy relaxation in [(NC)5RUIICNRuIII (NH3)3]1-

Abstract

Conference

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