Suppression of dense Kondo state in CeB<inf>6</inf> under pressure

To investigate whether the dense Kondo compound CeB6 might evolve into a topological insulator under sufficient pressure, four-point electrical resistivity measurements have been carried out over the temperature range 1.3 K-295 K in a diamond anvil cell to 122 GPa. The temperature Tmax of the resistivity maximum initially increases slowly with pressure but disappears between 12 and 20 GPa. The marked changes observed under pressure suggest that a valence and/or structural transition may have occurred. Synchrotron x-ray diffraction measurements, however, fail to detect any change in crystal structure to 85 GPa. Although a transition into an insulating phase is not observed, this dense Kondo system is completely suppressed at 43 GPa, leaving behind what appears to be a conventional Fermi liquid metal.