Synthesis and activity of co-doped barium cerium zirconate for hydrogen reforming and purification

Aravind Suresh; Joysurya Basu; Nigel M. Sammes; C. Barry Carter; A. Wilhite Benjamin

Synthesis and activity of co-doped barium cerium zirconate for hydrogen reforming and purification

Aravind Suresh
, Joysurya Basu
, Nigel M. Sammes
, C. Barry Carter
, A. Wilhite Benjamin

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Abstract

BaCe0.25Zr0.60Co0.15O3-x (BCZC) was synthesized via oxalate co-precipitation route. Material was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Catalytic activity of BCZC with respect to hydrogen generation via methanol partial oxidation was determined. Conductivity of the material at different temperatures and under different environments was determined by AC impedance spectroscopy. XRD and TEM results indicated that BCZC was synthesized as a homogeneous cubic phase material. Catalyst tests indicated that BCZC was catalytically active towards hydrogen generation and AC impedance results were positive enough to warrant further electrochemical studies.

Original language	English
Title of host publication	Materials Research Society Symposium Proceedings
Pages	139-144
Number of pages	6
Volume	1126
State	Published - Sep 25 2009
Externally published	Yes

Cite this

@inproceedings{cecbc7702be7474da3198c6be060220d,

title = "Synthesis and activity of co-doped barium cerium zirconate for hydrogen reforming and purification",

abstract = "BaCe0.25Zr0.60Co0.15O3-x (BCZC) was synthesized via oxalate co-precipitation route. Material was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Catalytic activity of BCZC with respect to hydrogen generation via methanol partial oxidation was determined. Conductivity of the material at different temperatures and under different environments was determined by AC impedance spectroscopy. XRD and TEM results indicated that BCZC was synthesized as a homogeneous cubic phase material. Catalyst tests indicated that BCZC was catalytically active towards hydrogen generation and AC impedance results were positive enough to warrant further electrochemical studies.",

author = "Aravind Suresh and Joysurya Basu and Sammes, \{Nigel M.\} and Carter, \{C. Barry\} and Benjamin, \{A. Wilhite\}",

year = "2009",

month = sep,

day = "25",

language = "English",

isbn = "9781605110981",

volume = "1126",

pages = "139--144",

booktitle = "Materials Research Society Symposium Proceedings",

}

TY - GEN

T1 - Synthesis and activity of co-doped barium cerium zirconate for hydrogen reforming and purification

AU - Suresh, Aravind

AU - Basu, Joysurya

AU - Sammes, Nigel M.

AU - Carter, C. Barry

AU - Benjamin, A. Wilhite

PY - 2009/9/25

Y1 - 2009/9/25

N2 - BaCe0.25Zr0.60Co0.15O3-x (BCZC) was synthesized via oxalate co-precipitation route. Material was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Catalytic activity of BCZC with respect to hydrogen generation via methanol partial oxidation was determined. Conductivity of the material at different temperatures and under different environments was determined by AC impedance spectroscopy. XRD and TEM results indicated that BCZC was synthesized as a homogeneous cubic phase material. Catalyst tests indicated that BCZC was catalytically active towards hydrogen generation and AC impedance results were positive enough to warrant further electrochemical studies.

AB - BaCe0.25Zr0.60Co0.15O3-x (BCZC) was synthesized via oxalate co-precipitation route. Material was characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Catalytic activity of BCZC with respect to hydrogen generation via methanol partial oxidation was determined. Conductivity of the material at different temperatures and under different environments was determined by AC impedance spectroscopy. XRD and TEM results indicated that BCZC was synthesized as a homogeneous cubic phase material. Catalyst tests indicated that BCZC was catalytically active towards hydrogen generation and AC impedance results were positive enough to warrant further electrochemical studies.

UR - https://www.scopus.com/pages/publications/70349266082

M3 - Conference contribution

SN - 9781605110981

VL - 1126

SP - 139

EP - 144

BT - Materials Research Society Symposium Proceedings

ER -

Synthesis and activity of co-doped barium cerium zirconate for hydrogen reforming and purification

Abstract

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