Tribological properties of alkylsilane self-assembled monolayers

In this study, we perform molecular dynamics simulations of adhesive contact and friction between alkylsilane Si(OH)3(CX2) 10CX3 and alkoxylsilane Si(OH)2(CX 2)10CX3 (where X = H or F) self-assembled monolayers (SAMs) on an amorphous silica substrate. The alkylsilane SAMs are primarily hydrogen-bonded or physisorbed to the surface. The alkoxylsilane SAMs are covalently bonded or chemisorbed to the surface. Previously, we studied the chemisorbed systems. In this work, we study the physisorbed systems and compare the tribological properties with the chemisorbed systems. Furthermore, we examine how water at the interface of the SAMs and substrate affects the tribological properties of the physisorbed systems. When less than a third of a monolayer is present, very little difference in the microscopic friction coefficient μ or shear stresses is observed. For increasing amounts of water, the values of μ and the shear stresses decrease; this effect is somewhat more pronounced for fluorocarbon alkylsilane SAMs than for the hydrocarbon SAMs. The observed decrease in friction is a consequence of a slip plane that occurs in the water as the amount of water is increased. We studied the frictional behavior using relative shear velocities ranging from v = 2 cm/s to 2 m/s. Similar to previously reported results for alkoxylsilane SAMs, the values of the measured stress and μ for the alkylsilane SAM systems decrease monotonically with v. © 2005 American Chemical Society.