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What is the entanglement length in a polymer melt?

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Abstract

We present the results of molecular dynamics simulations of very long model polymer chains analyzed by various experimentally relevant techniques. The segment motion of the chains is found to be in very good agreement with the reptation model. For comparison with experimental results we also calculated the plateau modulus G0N via stress-strain simulations. The predictions of the entanglement length Ne from G0N and from the mean-square dispacement of the chain segments disagree by a factor of about 2.3(2), indicating an error in the prefactor in the standard formula for G0N which is important for the analysis of many simulation results as well as the interpretation of experimental neutron spin echo (NSE) and NMR measurements. We explicitly show how recent NSE measurements are affected by this and some finite-size effects in the interpretation of the dynamic structure factor.
Original languageEnglish
Pages (from-to)735-741
Number of pages7
JournalEPL
Volume49
Issue number6
DOIs
StatePublished - Mar 11 2000
Externally publishedYes

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